3D Data Processing Toward Maintenance and Conservation. The Integrated Digital Documentation of Casa de Vidro

During the last decade, 3D integrated surveys and BIM modelling procedures have greatly improved the overall knowledge on some Brazilian Modernist buildings. In this framework, the Casa de Vidro 3D survey carried out by DIAPReM centre at Ferrara University, beside the important outputs, analysis and researches achieved from the point cloud database processing, was also useful to test several awareness increasing activities in cooperation with local stakeholders. The first digital documentation test of the Casa de Vidro allowed verifying the feasibility of a full survey on the building towards the restoration and possible placement of new architectures into the garden as an archive-museum of the Lina Bo and P.M. Bardi Foundation. Later, full 3D integrated survey and diagnostic analysis were carried out to achieve the total digital documentation of the house sponsored by the Keeping it Modern initiative of Getty Foundation (Los Angeles). Following its characteristics, the survey had to take into consideration the different architectural features, up to the relationship of architecture and nature. These 3D documentation activities and the point cloud processing allowed several analysis in a multidisciplinary framework

Fine tuning of MLCT states in new mononuclear complexes of ruthenium(II) containing tris(1-pyrazolyl)methane, 2,2′-bipyridine and aromatic nitrogen heterocycles

The syntheses of new mononuclear ruthenium(II) complexes of the type: [Ru(bpy)(L)(tpm)](PF6)2 {tpm = tris(1-pyrazolyl)-methane; bpy = 2,2′-bipyridine; L = pz (pyrazine; 1), 4,4′-bpy (4,4′-bipyridine; 2), and bpe [trans-1,2-bis(4-pyridyl)ethylene; 3]} are described, together with their spectroscopic, electrochemical, and photophysical properties. A complete assignment of the NMR resonances of the three species could be made in CD3CN by bidimensional techniques. A fine tuning of the energies of MLCT (metal-to-ligand charge transfer) states in these complexes is disclosed when comparing, in CH3CN, the values of their maximum absorption wave-lengths for the most intense visible bands (λ max) and their redox potentials for the RuIII/Ru II couples; this effect, relevant to the design of efficient photocatalysts, can be attributed to a decreasing order of dπ(Ru) →*(2,2′-bpy) backbonding when decreasing the distance between both N atoms in the aromatic nitrogen heterocycle L that acts in a monodentate manner. Only the species with L = bpe emits at room temperature, pointing to the conclusion that MLCT excited states in this series become higher in energy than dd excited states when the value of λmax is lower than 400 nm. These species are also useful building blocks for new dinuclear mixed-valent complexes. © Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.Fil: Katz, Néstor Eduardo. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química Física; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Romero, Isabel. Universidad de Girona; EspañaFil: Llobet, Antoni. Universidad de Girona; EspañaFil: Parella, Teodor. Universitat Autònoma de Barcelona; EspañaFil: Benet Buchholz, Jordi. Bayer Industry Services; Alemani

Innovative technologies for restoration in Pompeii. The 3D morphometric survey in via dell’Abbondanza

The project had as primary objectives the safeguarding of architectural remains and the experimentation with restoration methodologies and materials. The restoration works addressed a number of facades along the stretch of the Decumanus Maximus known today as via dell'Abbondanza. After the collection of numerous notes from previous archaeological investigations and from visual inspections about architectural morphology, materials and state of conservation, surveys of ancient facades were carried out and measurement data were collected. The survey by means of 3D laser scanner of the varied and complex architectures have been characterized by an attempt to focus efforts on contributing representational knowledge of the existing site elements

point cloud analysis for conservation and enhancement of modernist architecture

Documentation of cultural assets through improved acquisition processes for advanced 3D modelling is one of the main challenges to be faced in order to address, through digital representation, advanced analysis on shape, appearance and conservation condition of cultural heritage. 3D modelling can originate new avenues in the way tangible cultural heritage is studied, visualized, curated, displayed and monitored, improving key features such as analysis and visualization of material degradation and state of conservation. An applied research focused on the analysis of surface specifications and material properties by means of 3D laser scanner survey has been developed within the project of Digital Preservation of FAUUSP building, Faculdade de Arquitetura e Urbanismo da Universidade de São Paulo, Brazil. The integrated 3D survey has been performed by the DIAPReM Center of the Department of Architecture of the University of Ferrara in cooperation with the FAUUSP. The 3D survey has allowed the realization of a point cloud model of the external surfaces, as the basis to investigate in detail the formal characteristics, geometric textures and surface features. The digital geometric model was also the basis for processing the intensity values acquired by laser scanning instrument; this method of analysis was an essential integration to the macroscopic investigations in order to manage additional information related to surface characteristics displayable on the point cloud

INSPIRE PROJECT: INTEGRATED TECHNOLOGIES FOR SMART BUILDINGS AND PREDICTIVE MAINTENANCE

Abstract. Applying integrated digital technologies for the management and maintenance of the existing built heritage appears to be one of the main current challenges for the definition and application of digitisation protocols for the construction supply chain. Key enabling technologies, collaborative platforms, Big Data management and information integration in a BIM environment are areas of increasing experimentation. In the field of intervention on the built heritage, it is the boundaries and opportunities offered by the integration of many different information sources that constitutes the main challenge. Furthermore, the study of the accessibility and usability of data and information from sources such as the three-dimensional terrestrial survey, existing databases, sensor networks, and satellite technologies make it possible to investigate both different ways of data modelling, even with a view to the development of predictive algorithms, and of visualisation and information management. The study illustrates part of the results of the InSPiRE project, an industrial research project financed with European structural funds and carried out in a public-private partnership by four universities and public research bodies, an innovation centre and six companies, SMEs, large enterprises, and start-ups. Specifically, the project highlights the growing importance of BIM-based modelling as a tool to lead users, both experts and non-experts, through the multiple information paths resulting from the relation between data and metadata

PARAMETRICAL ANALYSIS AND DIGITAL FABRICATION OF THIN SHELL STRUCTURES: THE IMPACT OF CONSTRUCTION TECHNIQUE ON THE RESULTING GEOMETRY OF THE GAUSSIAN VAULTS OF ELADIO DIESTE

Abstract. The objective of this article is to analyze the state-of-art regarding the construction process of the Gaussian Vaults of the Uruguayan civil engineer Eladio Dieste and to identify the elements that underlie the relationship between the constructive techniques and procedures within this specific structural typology and its resulting geometry. As complementary objectives, this research aims for the identification of the gaps in the registry of such constructive procedures. The essay focuses on the geometry of the Gaussian Vaults designed and built by Dieste, in a way that these rigid structural surfaces' geometry had their original construction drawings redrawn and analyzed from the perspective of its construction technique by means of the Parametrical Modelling and Digital Fabrication of case studies.</p

Optimal refrigerator

We study a refrigerator model which consists of two $n$-level systems interacting via a pulsed external field. Each system couples to its own thermal bath at temperatures $T_h$ and $T_c$, respectively ($\theta\equiv T_c/T_h<1$). The refrigerator functions in two steps: thermally isolated interaction between the systems driven by the external field and isothermal relaxation back to equilibrium. There is a complementarity between the power of heat transfer from the cold bath and the efficiency: the latter nullifies when the former is maximized and {\it vice versa}. A reasonable compromise is achieved by optimizing the product of the heat-power and efficiency over the Hamiltonian of the two system. The efficiency is then found to be bounded from below by $\zeta_{\rm CA}=\frac{1}{\sqrt{1-\theta}}-1$ (an analogue of the Curzon-Ahlborn efficiency), besides being bound from above by the Carnot efficiency $\zeta_{\rm C} = \frac{1}{1-\theta}-1$. The lower bound is reached in the equilibrium limit $\theta\to 1$. The Carnot bound is reached (for a finite power and a finite amount of heat transferred per cycle) for $\ln n\gg 1$. If the above maximization is constrained by assuming homogeneous energy spectra for both systems, the efficiency is bounded from above by $\zeta_{\rm CA}$ and converges to it for $n\gg 1$.Comment: 12 pages, 3 figure

INVESTIGATIONS ON THE DESIGN PROCESS OF ELADIO DIESTE: 3D PARAMETRIC MODELLING OF MODERN LATIN AMERICAN ARCHITECTURAL HERITAGE

Abstract. The Uruguayan Engineer Eladio Dieste underwent a quest for thinness in the field of structural design which rendered his reinforced masonry thin-shell structures at a conspicuous position in Modern Latin American Architectural Heritage, so much so as to have Dieste's work in Latin America and Europe included in an indicative list for UNESCO's cultural heritage sites as of 2010. Nonetheless, the design process that led Dieste to such innovative structural typologies is yet to be fully academically explored. Thus, the objective of this paper is to examine the state-of-art regarding the intricate design process of Eladio Dieste's gaussian vaults and shed some light on the existing gaps within this process by means of the 3D parametric modelling and digital fabrication of selected case studies. The adoption methodological procedures such as 3D parametrical modelling and digital fabrication allows for the establishment of important relationships between the design process and the resulting geometry of Eladio Dieste's designs, as well as furthering registry of Dieste's legacy for conservation purposes.</p

Efficacy of adalimumab as second-line therapy in a pediatric cohort of crohn’s disease patients who failed infliximab therapy: The Italian society of pediatric gastroenterology, hepatology, and nutrition experience

Background: Adalimumab (Ada) treatment is an available option for pediatric Crohn’s disease (CD) and the published experience as rescue therapy is limited. Objectives: We investigated Ada efficacy in a retrospective, pediatric CD cohort who had failed previous infliximab treatment, with a minimum follow-up of 6 months. Methods: In this multicenter study, data on demographics, clinical activity, growth, laboratory values (CRP) and adverse events were collected from CD patients during follow-up. Clinical remission (CR) and response were defined with Pediatric CD Activity Index (PCDAI) score ≤10 and a decrease in PCDAI score of ≥12.5 from baseline, respectively. Results: A total of 44 patients were consecutively recruited (mean age 14.8 years): 34 of 44 (77%) had active disease (mean PCDAI score 24.5) at the time of Ada administration, with a mean disease duration of 3.4 (range 0.3–11.2) years. At 6, 12, and 18 months, out of the total of the enrolled population, CR rates were 55%, 78%, and 52%, respectively, with a significant decrease in PCDAI scores (P&lt;0.01) and mean CRP values (mean CRP 5.7 and 2.4 mL/dL, respectively; P&lt;0.01) at the end of follow-up. Steroid-free remission rates, considered as the total number of patients in CR who were not using steroids at the end of this study, were 93%, 95%, and 96% in 44 patients at 6, 12, and 18 months, respectively. No significant differences in growth parameters were detected. In univariate analysis of variables related to Ada efficacy, we found that only a disease duration &gt;2 years was negatively correlated with final PCDAI score (P&lt;0.01). Two serious adverse events were recorded: 1 meningitis and 1 medulloblastoma. Conclusion: Our data confirm Ada efficacy in pediatric patients as second-line biological therapy after infliximab failure. Longer-term prospective data are warranted to define general effectiveness and safety in pediatric CD patients